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  1. Free, publicly-accessible full text available July 23, 2024
  2. Recent decades have seen a significant increase in the frequency, intensity, and impact of natural disasters and other emergencies, forcing the governments around the world to make emergency response and disaster management national priorities. The growth of extremely large and complex datasets — commonly referred to as big data — and various advances in information and communications technology and computing now support more effective approaches to humanitarian relief, logistical coordination, overall disaster management, and long-term recovery in connection with natural disasters and emergency events. Leveraging big data and technological advances for emergency management has attracted considerable attention in the research community. However, the desired merging of big data and emergency management (BDEM) requires coordinated efforts to align and define interdisciplinary terminologies and methodologies. To date, the key concepts and technologies in this emerging research area have not been coherently discussed in a sufficiently broad and multidisciplinary manner. In this article, an international team presents an overview of the BDEM domain, highlighting a general framework and discussing key challenges from several perspectives. We introduce and summarize typical technologies and applications, organized into the six broad categories. Finally, we outline several directions of future research. 
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  3. Abstract

    We present the analysis of the atmospheric budget of nitrophenols and nitrocresols, a class of nitroaromatics that raise great ecosystem and health concerns due to their phytotoxic and genotoxic properties, during the spring wheat harvest season in Eastern China. Significant quantities with maximum concentrations over 100 pptv and distinct diurnal patterns that peak around midnight and maintain low levels throughout the day were observed, in coincidence with the extensive open crop residue burning activities conducted in the vicinity. An observationally constrained zero‐dimension box model was constructed to assess the relative importance of various production and removal pathways at play in determining the measured surface concentrations. The NO3‐initiated dark chemistry, in concert with meteorological variations predominantly dilution and entrainment, exerts major controls over the observed diurnal behaviors of nitrophenols and nitrocresols. Structural isomerism is predicted to have a significant impact on the multiphase partitioning and chemistry of nitrophenol isomers. Furthermore, simulations show that an appreciable amount of nitrophenols is present in the aerosol water, thereby representing an important source of water‐soluble brown carbon in atmospheric aerosols under the humid subtropical weather prevailing during the campaign. Sensitivity analysis performed on the model parameterizations of reaction schemes helps to further understand the chemistry underlying the diurnal cycles. Implementing NO‐dependent yields of cresols from toluene photooxidation improves the model predictions of nitrocresols at low NO ranges (<1 ppb), thereby underscoring the complexity of the peroxy radical reaction pathways from toluene photooxidation under atmospheric relevant conditions.

     
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